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• W3151926028 abstract "To minimize the physical loss of antioxidants, a novel reactive antioxidant (HP-Cl) was prepared and grafted onto the backbones of polyamide 6 (PA6) by the reactive extrusion with high grafting efficiency (PA6-g- HP). The structure and composition of HP-Cl and PA6-g- HP were characterized by FTIR, 1 H NMR, and UV spec- trum analysis. Both thermal degradation kinetics and migration kinetics of PA6-g-HP were studied by comparing with PA6/Irganox 245. It was found that the difference in the mass loss between the two samples became greater with increasing temperature and time, and the sample of PA6-g- HP had a relatively low thermal oxidation degradation rate constant (K). The average values of the activation energy (Ea) and frequency factor (A) of PA6-g-HP kept relatively stable and were much higher than that of PA6/Irganox 245 during degradation process. The migration of antiox- idants followed Fick's second law, and the equilibrium migration concentration and the diffusivity value of PA6/ Irganox 245 were much higher than that of PA6-g-HP. The results confirmed that the sample of PA6-g-HP exhibited excellent thermal stability and anti-migration property by in situ stabilization with reactive antioxidant." @default.
• W3151926028 created "2021-04-13" @default.
• W3151926028 creator A5030849542 @default.
• W3151926028 creator A5031347667 @default.
• W3151926028 date "2015-01-01" @default.
• W3151926028 modified "2023-09-26" @default.
• W3151926028 title "In situ stabilization of polyamide 6 with reactive antioxidant" @default.
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