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• W3152059657 abstract "Binary Mixture Flammability Characteristics for Hazard Assessment. (August 2005) Migvia del C. Vidal Vazquez, B.S., Universidad de Puerto Rico, Mayaguez, PR Chair of Advisory Committee: Dr. M. Sam Mannan Flammability is an important factor of safe practices for handling and storage of liquid mixtures and for the evaluation of the precise level of risk. Flash point is a major property used to determine the fire and explosion hazards of a liquid, and it is defined as the minimum temperature at which the vapor present over the liquid at equilibrium forms a flammable mixture when mixed with air. Experimental tests for the complete composition range of a mixture are time consuming, whereas a mixture flash point can be estimated using a computational method and available information. The information needed for mixture flash point predictions are flashpoints, vapor pressures, and activity coefficients as functions of temperature for each mixture component. Generally, sufficient experimental data are unavailable and other ways of determining the basic information are needed. A procedure to evaluate the flash point of binary mixtures is proposed, which provides techniques that can be used to estimate a parameter that is needed for binary mixture flash point evaluations. Minimum flash point behavior (MFPB) is exhibited when the flash point of the mixture is below the flash points of the individual components of the mixture. The identification of this behavior is critical, because a hazardous situation results from taking the lowest component flash point value as the mixture flash point. Flash point predictions were performed for 14 binary mixtures using various G models for the activity coefficients. Quantum chemical calculations and UNIFAC, a theoretical model that does not require experimental binary interaction parameters, are" @default.
• W3152059657 created "2021-04-13" @default.
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• W3152059657 date "2005-01-01" @default.
• W3152059657 modified "2023-09-27" @default.
• W3152059657 title "BINARY MIXTURE FLAMMABILITY CHARACTERISTICS FOR HAZARD ASSESSMENT" @default.
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