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- W3152080287 abstract "A diastereoselective [4 + 2] cycloisomerization of asymmetric allenyl dienes is reported. The asymmetric dienyl allenes are synthesized using the method reported by Ma. These substrates readily undergo diastereoselective intramolecular rhodium catalyzed [4 + 2] cycloisomerization analogous to thermal intramolecular Diels–Alder reactions. Overall, 29 examples are presented with tethers possessing nitrogen, oxygen, and carbon. Diastereoselectivities range from 99:1 to 90:10 in most examples." @default.
- W3152080287 created "2021-04-13" @default.
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- W3152080287 date "2021-03-30" @default.
- W3152080287 modified "2023-09-26" @default.
- W3152080287 title "Diastereoselective Rhodium Catalyzed [4 + 2] Cycloisomerization of Allenes" @default.
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- W3152080287 doi "https://doi.org/10.1021/acs.orglett.1c00554" @default.
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