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- W3152102732 abstract "Two Cd(Ⅱ) coordination polymers [Cd3Na2(btec)2(H2O)2]n(1) and {[Cd3Na2(btec)2·(H2O)2]·4H2O} n(2)(H4btec=1,2,4,5-benzenetetracarboxylic acid) were synthesized by hydrothermal method.The structures were determined by single crystal X-ray diffraction.Structural analyses show that the asymmetric units of polymers 1 and 2 contain two crystallographically unique Cd(Ⅱ) ions with six-and eight-coordinate,respectively,and they possess 3D structures bridged by btec4-groups.The structure differences between them are that the coordination environment around Na(Ⅰ) ions is different and polymer 2 has lattice water molecules.The photo-electric properties of the two polymers were investigated by surface photovoltage spectroscopy(SPS).The results of SPS show that the two polymers exhibit obvious photovoltage responses in the range of 300—500 nm,which indicates that they all possess certain photo-electric conversion properties.The SPS and UV-Vis spectra of the polymers were interrelated,and XRD patterns and TG curves of the two polymers were measured and analyzed." @default.
- W3152102732 created "2021-04-13" @default.
- W3152102732 creator A5091271273 @default.
- W3152102732 date "2013-01-01" @default.
- W3152102732 modified "2023-09-25" @default.
- W3152102732 title "Syntheses,Structures and Surface Photo-electric Properties of Cd(II)-btec Coordination Polymers" @default.
- W3152102732 hasPublicationYear "2013" @default.
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