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- W3152131907 abstract "Secondary amides are a class of highly stable compounds serving as versatile starting materials,intermediates and directing groups(amido groups) in organic synthesis.The direct deacylation of secondary amides to release amines is an important transformation in organic synthesis.Here,we report a protocol for the deacylation of secondary amides and isolation of amines.The method is based on the activation of amides with Tf_2O.followed by addition of organocerium reagents,and acidic work-up.The reaction proceeded under mild conditions and afforded the corresponding amines,isolated as their hydrochloride salts,in good yields.In combination with the C-H activation functionalization methodology,the method is applicable to the functionalization of aniline as well as conversion of carboxylic derivatives to functionalized ketones." @default.
- W3152131907 created "2021-04-13" @default.
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- W3152131907 date "2015-01-01" @default.
- W3152131907 modified "2023-09-23" @default.
- W3152131907 title "Mild N-deacylation of secondary amides by alkylation with organocerium reagents" @default.
- W3152131907 hasPublicationYear "2015" @default.
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