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- W3152151 abstract "Publisher Summary Optical Raman heterodyne detection (RHD) of nuclear magnetic resonance (NMR) in low-temperature solids has been demonstrated to be a sensitive and powerful spectroscopic technique. For superhyperfine (shf) spectra, the radio frequency and optical photons are absorbed by different atoms—Al and Cr, respectively. The Raman transitions are activated by the exchange and dipole coupling between Al and Cr ions. This chapter describes an experiment in which nuclear spin dephasing was observed in the frozen core. In this experiment, RHD from its original application was extended to hyperfine (hf) spectra of rare earth ions to shf spectra of Al in ruby. A very dilute sample of ruby was used to minimize effects of Cr–Cr spin flipping on the Al dephasing time. According to this experiment, nuclei close to a paramagnetic ion does not undergo spin flips with those in the bulk because of detuning. Thus, the dephasing time of Al ions in the frozen core is expected to be much longer than that in the bulk." @default.
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- W3152151 date "1989-01-01" @default.
- W3152151 modified "2023-09-27" @default.
- W3152151 title "Nuclear Spin Dephasing in the Frozen Core" @default.
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- W3152151 doi "https://doi.org/10.1016/b978-0-12-251930-7.50104-7" @default.
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