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- W3152243553 abstract "Two new porphyrin-Salen type ligands 5-(3-amino-4-(3,5-di-tert-butylsalicylidene)aminophenyl)-10,15,20-triphenylporphyrin(1) and 5-(N,N'-di(3,5-di-tert-butylsalicylidene)-3,4-diaminophenyl)-10,15,20-triphenylporphyrin(2), their homo- and hetero- binuclear metal complexes and their mononuclear metal complexes were synthesized and characterized by 1 H nuclear magnetic resonance(1H NMR) spectroscopy,electrospray ionization mass spectrometry(ESI-MS), elemental analysis, Fourier transform infrared(FTIR)spectroscopy, and ultraviolet visible(UV-Vis) spectroscopy. The third-order nonlinear optical properties of these ligands and complexes were investigated by Z scan techniques. Experimental results indicated that ligands 1 and 2 have a close strong reverse-saturable absorption and self-defocusing effect. The polarization induced by the coordinated metal ions affects the nonlinear refractive indexes of these ligands." @default.
- W3152243553 created "2021-04-13" @default.
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- W3152243553 date "2014-01-01" @default.
- W3152243553 modified "2023-09-23" @default.
- W3152243553 title "Synthesis and Nonlinear Optical Properties of Porphyrin-Salen Type Homo-and Hetero-Binuclear Metal Complexes" @default.
- W3152243553 hasPublicationYear "2014" @default.
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