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- W3152255810 abstract "Abstract We represent here, a divergent approach for the total synthesis of (±)‐Mahanine and twelve other naturally occurring carbazole alkaloids. Remarkably, we have utilized a simplified scalable Suzuki coupling for C−C bond formation and a metal‐free C−N coupling sequence to synthesize the functionalized carbazole scaffold from a single intermediate. Subsequently, either functional group manipulations or late‐stage pyran ring annulation furnished a library of 13 carbazole alkaloids mostly isolated from a traditional medicinal plant Murraya koenigii . The construction of carbazole moiety at the initial‐stage followed by late‐stage pyran annulation under mild condition overcomes the decomposition problem of pyran‐ring under acidic or other harsh reaction conditions." @default.
- W3152255810 created "2021-04-13" @default.
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- W3152255810 date "2021-04-15" @default.
- W3152255810 modified "2023-09-23" @default.
- W3152255810 title "Divergent Total Synthesis of (±)‐Mahanine and Other Carbazole Alkaloids" @default.
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- W3152255810 doi "https://doi.org/10.1002/ajoc.202100176" @default.
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