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- W3152483578 abstract "与与苯戒指上的不同 R 组一起的本甲基组(QARBC ) 一起的一系列 cationic surfmers 被红外综合并且描绘, 1H-NMR, 13C-NMR。QARBC 的聚集被不变的荧光技术学习。结果,有的表面活动和他们的批评 micelle 集中(CMC ) 珍视的 QARBC 在 10 的范围变化了 ? 210 ? 有有温度的细微增加的 3 mol/L。acrylamide (M1 ) 和 QARBC (M2 ) 的 copolymerization 被学习在下面并且在 CMC 上面,他们的反应比率被 Finemann 粗糙表面方法决定。在 CMC 下面, copolymerization 在一个同类的系统和 acrylamide 的反应比率发生了, QARBC 是不到 1,这被发现;当时上面的 CMC, QARBC 的反应比率比 1 大。QARBC 的 copolymerization 机制被观察类似于 micellar 聚合的。QARBC 趋于到 homopolymerization,它在聚合物脊梁产生了微短而粗的序列。QARBC 的 Q 和 e 价值被使用 r 根据 Alfrey 价格方程计算 1 (AM ) 并且 r 2 (QARBC ) 。样品(AM-co-QARBC ) poly 上面被准备,下面, CMC 和他们的恐水病的协会被不变的荧光系列和 2D NOESY 系列学习,并且他们的批评联系集中(CAC ) 被估计。结果证明那取样(AM-co-QARBC ) poly 比在 CMC 下面准备的那些在水的答案在 CMC 上面准备了有的更强壮的恐水病的协会。" @default.
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- W3152483578 date "2011-01-01" @default.
- W3152483578 modified "2023-09-23" @default.
- W3152483578 title "CATIONIC SURFMERS WITH BENZYL GROUPS: SYNTHESIS AND COPOLYMERIZATION WITH ACRYLAMIDE" @default.
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