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- W3153529602 abstract "We developed a series of water-soluble NHC-capped CD metal complexes, called (ICyD)MeMCl (M = Ag, Au, Cu). All (ICyD)MeMCl complexes were first characterized by NMR in organic solvents. X-ray crystal structures of (α-ICyD)MeMCl were obtained in both CDCl3 and water, while single crystal of (α-ICyD)MeCuCl, (β-ICyD)MeHCl and (β-ICyD)MeAuCl were obtained in CDCl3, CD2Cl2 and acetone-d6, respectively. Capitalizing on the good water solubility of (ICyD)MeMCl complexes, they were also used as catalysts in hydration, lactonization, hydroarylation and cycloisomerization reactions in pure water. We captured monomeric copper hydride species (α-ICyD)BnCuH and fully characterized it by NMR for the first time. A completely chemoselective 1,2-addition on α,β-unsaturated ketone was observed when using (α-ICyD)BnCuH. Two monomeric silver hydride species (α-ICyD)BnAgH and (α-ICyD)MeAgH were also synthesized at the same time. Using HI, it is possible to fully debenzylate the 3-positions on the secondary rim of benzylated CDs. We first synthesized a new type of NHC-capped CD metal complexes, called (α-ICyD)Bn,MeMCl (M = Ag, Au). Due to the asymmetric O-protection on the secondary rim of (α-ICyD)Bn,MeAuCl, it gave the highest ees in an enantioselective cycloisomeriations of 1,6-enynes compared with (α-ICyD)BnAuCl and (α-ICyD)MeAuCl complexes." @default.
- W3153529602 created "2021-04-26" @default.
- W3153529602 creator A5039451564 @default.
- W3153529602 date "2020-07-08" @default.
- W3153529602 modified "2023-09-28" @default.
- W3153529602 title "Metal Complexes Encapsulated inside Modified Cyclodextrins" @default.
- W3153529602 hasPublicationYear "2020" @default.
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