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- W3153648767 abstract "• Quinoa seed was used as a new eco-friendly corrosion inhibitor. • The adsorption of quinoa seed on the carbon steel surface was Langmuir mode. • The inhibition efficiency increased from 85 to 98%, based on polarization data. • The activation energy for corrosion reactions increased to 168.4 kJ/mol.K. Using green (eco-friendly) inhibitors to prevent metal corrosion is one of the global demands because of their nature-friendly features. Quinoa seed as a green effective inhibitor significantly lowered the corrosion rate of various materials. Herein, the first measurements of the inhibition performance of quinoa seed on corrosion behavior of carbon steel were reported. In particular, the corrosion behavior of carbon steel in 1 M HCl solution was studied using electrochemical tests including Tafel polarization and electrochemical impedance spectroscopy (EIS). Tafel polarization analysis revealed that the inhibition efficiency range reached 85–98% when the inhibitor concentration in the solution is 0.25–4 g/L. Besides, atomic force microscopy and field–emission scanning electron microscopy techniques were utilized to study the surfaces of corroded specimens. The highest inhibition efficiency measured for 2 g/L quinoa seed. Tafel polarization and EIS calculations indicated that the adsorption of quinoa seed molecules on the steel substrate followed the Langmuir isotherm mechanism where the physical adsorption energy (Δ G ° ads ) found to be about −17 kJ/mol. It was also found that, by increasing temperature up to 313 K, the inhibition efficiency decreased down to 86.9% when the inhibitor concentration was 2 g/L. To further analyze the adsorption behavior of quinoa seed on the carbon steel surface, molecular dynamics simulation, and ab-initio calculations were performed. This study is of interest to many experimental and theoretical groups and has great application potential in industries." @default.
- W3153648767 created "2021-04-26" @default.
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- W3153648767 date "2021-08-01" @default.
- W3153648767 modified "2023-09-30" @default.
- W3153648767 title "The inhibition performance of quinoa seed on corrosion behavior of carbon steel in the HCl solution; theoretical and experimental evaluations" @default.
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- W3153648767 doi "https://doi.org/10.1016/j.molliq.2021.116183" @default.
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