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• W3153670644 abstract "Abstract Synthetic transformations of otherwise inert C–H bonds have emerged as a powerful tool for molecular modifications during the last decades, with broad applications towards pharmaceuticals, material sciences, and crop protection. Consistently, a key challenge in C–H activation chemistry is the full control of site-selectivity. In addition to substrate control through steric hindrance or kinetic acidity of C–H bonds, one important approach for the site-selective C–H transformation of arenes is the use of chelation-assistance through directing groups, therefore leading to proximity-induced ortho-C–H metalation. In contrast, more challenging remote C–H activations at the meta- or para-positions continue to be scarce. Within this review, we demonstrate the distinct character of ruthenium catalysis for remote C–H activations until March 2021, highlighting among others late-stage modifications of bio-relevant molecules. Moreover, we discuss important mechanistic insights by experiments and computation, illustrating the key importance of carboxylate-assisted C–H activation with ruthenium(II) complexes. 1 Introduction 2 Stoichiometric Remote C–H Functionalizations 3 meta-C–H Functionalizations 4 para-C–H Functionalizations 5 meta-/ortho-C–H Difunctionalizations 6 Conclusions" @default.
• W3153670644 created "2021-04-26" @default.
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• W3153670644 date "2021-04-19" @default.
• W3153670644 modified "2023-09-24" @default.
• W3153670644 title "Remote C–H Functionalizations by Ruthenium Catalysis" @default.
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• W3153670644 doi "https://doi.org/10.1055/a-1485-5156" @default.
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