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- W3153848533 abstract "A four-coordinate cobalt–imido complex, (tBumPNP)Co=NMes (tBumPNP=modified PNP pincer ligand) has been synthesized from addition of 2,4,6-trimethylphenylazide (Mes–N3) to the corresponding dinitrogen complex. The solid-state structure determined by X-ray diffraction established a rare, idealized planar geometry with a Co=N bond distance of 1.716(2) Å. Magnetic measurements revealed an S=1 ground state with CAS-SCF calculations supporting radical character on the imide nitrogen. Thermolysis of the cobalt–imido compound induced selective insertion of the imido group into a Co−P bond and yielded a three-coordinate cobalt complex with a distorted T-shaped geometry. Transition state analysis conducted with DFT calculations established the thermodynamic stability of the P–N coupled product and provided insight into the exclusive selectivity." @default.
- W3153848533 created "2021-04-26" @default.
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- W3153848533 date "2021-05-24" @default.
- W3153848533 modified "2023-10-11" @default.
- W3153848533 title "Synthesis, Electronic Structure, and Reactivity of a Planar Four‐Coordinate, Cobalt–Imido Complex" @default.
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- W3153848533 doi "https://doi.org/10.1002/anie.202104320" @default.
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