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- W3153962051 abstract "• The Thermodynamic parameters of the three synthesized ILs were obtained. • Proposed the polarity coefficient P y and used to compared the polarities of ILs. • The surface tensions of the three synthesized ILs were predicted. Ether-based functionalized amino acid ionic liquids have the advantages of its unique Contribution to low viscosity and high conductivity, as well as the biodegradability of amino acids. Three kinds of ether-based functionalized amino acid ionic liquids 1-(4-methoxybutyl)-3-methylimidazolium glycine ([COC 4 mim][Gly]), 1-(4-methoxybutyl)-3-methylimidazolium alanine ([COC 4 mim][Ala]) and 1-(4-methoxybutyl)-3-methylimidazolium threonine ([COC 4 mim][Thr]) were synthesized. And physicochemical properties, including density, surface tension and refraction, were measured at different experimental conditions. Based on the polarity scale of ionic liquids proposed by Hildebrand theory, an equation of the polarity coefficient P y was proposed. And we found that it can be applied into the determination of polarity for both ionic liquids and molecular liquids. The surface tension of [COC 4 mim][Gly], [COC 4 mim][Ala] and [COC 4 mim][Thr] was estimated by the definitions of the molar surface Gibbs energy and molar refraction. The predicted values γ (pre) have a very high linear correlation with the corresponding experimental ones." @default.
- W3153962051 created "2021-04-26" @default.
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- W3153962051 date "2021-08-01" @default.
- W3153962051 modified "2023-09-30" @default.
- W3153962051 title "Study on the polarity and molar surface Gibbs energy of ether-based amino acid ionic liquids [COC4mim][Gly], [COC4mim][Ala] and [COC4mim][Thr]" @default.
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- W3153962051 doi "https://doi.org/10.1016/j.molliq.2021.116094" @default.
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