Matches in SemOpenAlex for { <https://semopenalex.org/work/W3154356586> ?p ?o ?g. }
- W3154356586 endingPage "5429" @default.
- W3154356586 startingPage "5422" @default.
- W3154356586 abstract "NaNbO3 enriched with oxygen vacancies by Ni doping was successfully synthesized via a polymerized complex method and applied as a photocatalyst in the oxidation of cinnamyl alcohol (CA) to cinnamaldehyde in air. Reaction rates as high as 45 μmol h–1 were achieved under visible light with a high apparent quantum efficiency of 67.2% and excellent chemoselectivity larger than 99%. UV–vis, electron paramagnetic resonance, and attenuated total reflectance infrared spectroscopy results indicate that the CA molecules preferentially adsorb at the oxygen vacancies, thus enabling electron transfer between coordinatively bound CA and NaNbO3 under visible light, inducing CA oxidation. The photocatalytic aerobic oxidation of CA is assumed to proceed via the one-photon pathway with H2O2 as the coupled product. The photodeposited Pt nanoparticles on the surface not only enhanced the oxidation rate but also improved the selectivity to cinnamaldehyde substantially because of the fast decomposition of formed H2O2, in this way avoiding its consecutive oxidation by H2O2. The oxygen vacancies on the surface generated by Ni doping are identified to play a decisive role in the chemisorption of cinnamyl alcohol and the interface charge transfer." @default.
- W3154356586 created "2021-04-26" @default.
- W3154356586 creator A5006914411 @default.
- W3154356586 creator A5016199067 @default.
- W3154356586 creator A5020380510 @default.
- W3154356586 creator A5022799331 @default.
- W3154356586 creator A5024753658 @default.
- W3154356586 creator A5026104775 @default.
- W3154356586 creator A5026930069 @default.
- W3154356586 creator A5039691617 @default.
- W3154356586 creator A5064182158 @default.
- W3154356586 creator A5069735009 @default.
- W3154356586 creator A5073316327 @default.
- W3154356586 creator A5077991577 @default.
- W3154356586 creator A5086597176 @default.
- W3154356586 date "2021-04-09" @default.
- W3154356586 modified "2023-10-03" @default.
- W3154356586 title "Highly Efficient and Selective Aerobic Oxidation of Cinnamyl Alcohol under Visible Light over Pt-Loaded NaNbO<sub>3</sub> Enriched with Oxygen Vacancies by Ni Doping" @default.
- W3154356586 cites W1580350362 @default.
- W3154356586 cites W1964101020 @default.
- W3154356586 cites W1964212175 @default.
- W3154356586 cites W2003611351 @default.
- W3154356586 cites W2028967540 @default.
- W3154356586 cites W2068631906 @default.
- W3154356586 cites W2068828768 @default.
- W3154356586 cites W2077301752 @default.
- W3154356586 cites W2094840081 @default.
- W3154356586 cites W2096978054 @default.
- W3154356586 cites W2114351642 @default.
- W3154356586 cites W2117867250 @default.
- W3154356586 cites W2131405326 @default.
- W3154356586 cites W2149766108 @default.
- W3154356586 cites W2290516063 @default.
- W3154356586 cites W2396680254 @default.
- W3154356586 cites W2501345610 @default.
- W3154356586 cites W2580779841 @default.
- W3154356586 cites W2592308660 @default.
- W3154356586 cites W2606356150 @default.
- W3154356586 cites W2665610964 @default.
- W3154356586 cites W2673841046 @default.
- W3154356586 cites W2748607929 @default.
- W3154356586 cites W2762252875 @default.
- W3154356586 cites W2766278009 @default.
- W3154356586 cites W2767692926 @default.
- W3154356586 cites W2792835090 @default.
- W3154356586 cites W2794053970 @default.
- W3154356586 cites W2795985100 @default.
- W3154356586 cites W2800403678 @default.
- W3154356586 cites W2807378414 @default.
- W3154356586 cites W2884778317 @default.
- W3154356586 cites W2895021294 @default.
- W3154356586 cites W2911267256 @default.
- W3154356586 cites W2914713851 @default.
- W3154356586 cites W2940258960 @default.
- W3154356586 cites W2942746554 @default.
- W3154356586 cites W2952946119 @default.
- W3154356586 cites W2955090842 @default.
- W3154356586 cites W2966086834 @default.
- W3154356586 cites W2969164476 @default.
- W3154356586 doi "https://doi.org/10.1021/acssuschemeng.1c00460" @default.
- W3154356586 hasPublicationYear "2021" @default.
- W3154356586 type Work @default.
- W3154356586 sameAs 3154356586 @default.
- W3154356586 citedByCount "13" @default.
- W3154356586 countsByYear W31543565862021 @default.
- W3154356586 countsByYear W31543565862022 @default.
- W3154356586 countsByYear W31543565862023 @default.
- W3154356586 crossrefType "journal-article" @default.
- W3154356586 hasAuthorship W3154356586A5006914411 @default.
- W3154356586 hasAuthorship W3154356586A5016199067 @default.
- W3154356586 hasAuthorship W3154356586A5020380510 @default.
- W3154356586 hasAuthorship W3154356586A5022799331 @default.
- W3154356586 hasAuthorship W3154356586A5024753658 @default.
- W3154356586 hasAuthorship W3154356586A5026104775 @default.
- W3154356586 hasAuthorship W3154356586A5026930069 @default.
- W3154356586 hasAuthorship W3154356586A5039691617 @default.
- W3154356586 hasAuthorship W3154356586A5064182158 @default.
- W3154356586 hasAuthorship W3154356586A5069735009 @default.
- W3154356586 hasAuthorship W3154356586A5073316327 @default.
- W3154356586 hasAuthorship W3154356586A5077991577 @default.
- W3154356586 hasAuthorship W3154356586A5086597176 @default.
- W3154356586 hasConcept C114157696 @default.
- W3154356586 hasConcept C121332964 @default.
- W3154356586 hasConcept C150394285 @default.
- W3154356586 hasConcept C161790260 @default.
- W3154356586 hasConcept C178790620 @default.
- W3154356586 hasConcept C185592680 @default.
- W3154356586 hasConcept C187961010 @default.
- W3154356586 hasConcept C2777435628 @default.
- W3154356586 hasConcept C2777516457 @default.
- W3154356586 hasConcept C2780440420 @default.
- W3154356586 hasConcept C2781066024 @default.
- W3154356586 hasConcept C33790079 @default.
- W3154356586 hasConcept C46141821 @default.
- W3154356586 hasConcept C540031477 @default.
- W3154356586 hasConcept C65165184 @default.
- W3154356586 hasConcept C75473681 @default.
- W3154356586 hasConceptScore W3154356586C114157696 @default.