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- W3154393311 abstract "Abstract In this work, the first diboron reagent initiated atom-transfer radical cyclization was reported, in which the boryl radicals were generated by the homolytic cleavage of a B–B single bond weakened by the coordination of Lewis base. To clarify the role of carbonate and DMF in the cleavage of B–B bond, we calculated the free energy diagram of two pathways by density functional theory (DFT) investigations. The DFT calculation showed that the presence of carbonate facilitates the B–B bond cleavage to form boron radicals, which can be further stabilized by DMF. Subsequent atom-transfer cyclization initiated by stabilized dihydroxyboron radical is also energetically favored." @default.
- W3154393311 created "2021-04-26" @default.
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- W3154393311 date "2021-04-19" @default.
- W3154393311 modified "2023-09-26" @default.
- W3154393311 title "Tetrahydroxydiboron-Initiated Atom-Transfer Radical Cyclization" @default.
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- W3154393311 doi "https://doi.org/10.1055/a-1485-4956" @default.
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