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- W3154647049 abstract "Biological macromolecules always function through a collective behavior of the aggregated constituents, which usually are self-assembled together via noncovalent interactions. Likewise, artificial supramolecular assemblies, whose properties and functions are mainly derived from their primary and secondary structures, may also aggregate into high-order architectures with emergent functions not available on the individual components. Here we report the first example of an insulin-like hexamerization of lanthanide triple helicates toward a 4 nm diameter hexameric capsule via consecutive metal-directed and anion-directed assembly processes. Hierarchical chiral-sorting self-assembly endows hexamers with aggregation-induced stability and emission enhancement. Furthermore, emergent guest-encapsulation function and enantioselectivity toward terpene drugs have been realized in the late-formed central cavity of the hexamers. This study not only provides a feasible strategy for constructing sophisticated and multifunctional lanthanide–organic materials but also sheds some light on the self-assembly processes in nature." @default.
- W3154647049 created "2021-04-26" @default.
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- W3154647049 date "2021-04-19" @default.
- W3154647049 modified "2023-10-17" @default.
- W3154647049 title "Hexameric Lanthanide–Organic Capsules with Tertiary Structure and Emergent Functions" @default.
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- W3154647049 doi "https://doi.org/10.1021/jacs.1c01168" @default.
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- W3154647049 hasPublicationYear "2021" @default.
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