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• W3154683546 abstract "In order to fine tune the morphology of an anodic network, the understanding of the basic electrochemical mechanisms involved is required. The purpose of the present paper is to study the formation of the anodic aluminum oxide (AAO) on 5657 aluminum alloy in H3PO4 when varying the electrolyte concentration (0.1 M – 2 M) and the applied voltage (0–300 V) using a combination of in situ electrochemical investigations and SEM morphological observations.Even if the anodizing voltage and the electrolyte concentration enhance the anodizing rate, the thickness of the anodic film remains limited to 13 µm whatever the electrochemical conditions. The presence of alloying elements induces morphological specificities: the cyclic accumulation/dissolution of the noble elements leads to the formation of regularly spaced transversal pores in the alumina wall. Finally, by selecting appropriate chemical and electrochemical conditions, the fabrication of AAO layer with large and regular pores (until 150 nm of diameter) is possible with a suitable growth rate (0.2 µm min−1 at 90 V in 1 M H3PO4) on the considered commercial complex aluminum alloys." @default.
• W3154683546 created "2021-04-26" @default.
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• W3154683546 date "2021-06-01" @default.
• W3154683546 modified "2023-10-13" @default.
• W3154683546 title "Large-pores anodizing of 5657 aluminum alloy in phosphoric acid: an in-situ electrochemical study" @default.
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• W3154683546 doi "https://doi.org/10.1016/j.electacta.2021.138303" @default.
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