Matches in SemOpenAlex for { <https://semopenalex.org/work/W3154736501> ?p ?o ?g. }
- W3154736501 endingPage "6227" @default.
- W3154736501 startingPage "6207" @default.
- W3154736501 abstract "The binary hydride, diisobutylaluminum borohydride [(iBu)2AlBH4], synthesized from diisobutylaluminum hydride (DIBAL) and borane dimethyl sulfide (BMS) has shown great potential in reducing a variety of organic functional groups. This unique binary hydride, (iBu)2AlBH4, is readily synthesized, versatile, and simple to use. Aldehydes, ketones, esters, and epoxides are reduced very fast to the corresponding alcohols in essentially quantitative yields. This binary hydride can reduce tertiary amides rapidly to the corresponding amines at 25 °C in an efficient manner. Furthermore, nitriles are converted into the corresponding amines in essentially quantitative yields. These reactions occur under ambient conditions and are completed in an hour or less. The reduction products are isolated through a simple acid–base extraction and without the use of column chromatography. Further investigation showed that (iBu)2AlBH4 has the potential to be a selective hydride donor as shown through a series of competitive reactions. Similarities and differences between (iBu)2AlBH4, DIBAL, and BMS are discussed." @default.
- W3154736501 created "2021-04-26" @default.
- W3154736501 creator A5004858290 @default.
- W3154736501 creator A5008633424 @default.
- W3154736501 creator A5018781337 @default.
- W3154736501 creator A5028763469 @default.
- W3154736501 creator A5048982318 @default.
- W3154736501 creator A5052470741 @default.
- W3154736501 creator A5071566374 @default.
- W3154736501 date "2021-04-12" @default.
- W3154736501 modified "2023-10-17" @default.
- W3154736501 title "Reaction of Diisobutylaluminum Borohydride, a Binary Hydride, with Selected Organic Compounds Containing Representative Functional Groups" @default.
- W3154736501 cites W1963782297 @default.
- W3154736501 cites W1968751587 @default.
- W3154736501 cites W1979030425 @default.
- W3154736501 cites W1981559964 @default.
- W3154736501 cites W1987788840 @default.
- W3154736501 cites W1991971314 @default.
- W3154736501 cites W1995713021 @default.
- W3154736501 cites W1997027171 @default.
- W3154736501 cites W2001067738 @default.
- W3154736501 cites W2003862801 @default.
- W3154736501 cites W2005602877 @default.
- W3154736501 cites W2010885175 @default.
- W3154736501 cites W2011846059 @default.
- W3154736501 cites W2012323328 @default.
- W3154736501 cites W2015987147 @default.
- W3154736501 cites W2021024290 @default.
- W3154736501 cites W2022206624 @default.
- W3154736501 cites W2022861984 @default.
- W3154736501 cites W2025201155 @default.
- W3154736501 cites W2028576398 @default.
- W3154736501 cites W2030209541 @default.
- W3154736501 cites W2032550042 @default.
- W3154736501 cites W2033252729 @default.
- W3154736501 cites W2039340543 @default.
- W3154736501 cites W2046575256 @default.
- W3154736501 cites W2051195727 @default.
- W3154736501 cites W2054971399 @default.
- W3154736501 cites W2062983504 @default.
- W3154736501 cites W2067001057 @default.
- W3154736501 cites W2068051679 @default.
- W3154736501 cites W2068936058 @default.
- W3154736501 cites W2069746098 @default.
- W3154736501 cites W2070233657 @default.
- W3154736501 cites W2070992836 @default.
- W3154736501 cites W2075551687 @default.
- W3154736501 cites W2079893389 @default.
- W3154736501 cites W2080379656 @default.
- W3154736501 cites W2084415012 @default.
- W3154736501 cites W2086631541 @default.
- W3154736501 cites W2090685138 @default.
- W3154736501 cites W2093061203 @default.
- W3154736501 cites W2098123118 @default.
- W3154736501 cites W2112941738 @default.
- W3154736501 cites W2117643210 @default.
- W3154736501 cites W2119274070 @default.
- W3154736501 cites W2123766854 @default.
- W3154736501 cites W2129893094 @default.
- W3154736501 cites W2145113276 @default.
- W3154736501 cites W2155716084 @default.
- W3154736501 cites W2159269324 @default.
- W3154736501 cites W2171676107 @default.
- W3154736501 cites W2273752190 @default.
- W3154736501 cites W2312657495 @default.
- W3154736501 cites W2313559347 @default.
- W3154736501 cites W2320819664 @default.
- W3154736501 cites W2323072657 @default.
- W3154736501 cites W2323163306 @default.
- W3154736501 cites W2323313338 @default.
- W3154736501 cites W2324934025 @default.
- W3154736501 cites W2325904980 @default.
- W3154736501 cites W2332479826 @default.
- W3154736501 cites W2334786320 @default.
- W3154736501 cites W2335025196 @default.
- W3154736501 cites W2602935923 @default.
- W3154736501 cites W2618906256 @default.
- W3154736501 cites W2735419424 @default.
- W3154736501 cites W2749618873 @default.
- W3154736501 cites W2755657956 @default.
- W3154736501 cites W2783036413 @default.
- W3154736501 cites W2791864880 @default.
- W3154736501 cites W2899659978 @default.
- W3154736501 cites W2909835348 @default.
- W3154736501 cites W2914539294 @default.
- W3154736501 cites W2949220826 @default.
- W3154736501 cites W2949745197 @default.
- W3154736501 cites W2950110253 @default.
- W3154736501 cites W2953314151 @default.
- W3154736501 cites W2970795524 @default.
- W3154736501 cites W2980869145 @default.
- W3154736501 cites W2982412928 @default.
- W3154736501 cites W2990275921 @default.
- W3154736501 cites W3004135815 @default.
- W3154736501 cites W3033903920 @default.
- W3154736501 cites W4250669383 @default.
- W3154736501 doi "https://doi.org/10.1021/acs.joc.0c03062" @default.
- W3154736501 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33843216" @default.