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- W3154874517 endingPage "6671" @default.
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- W3154874517 abstract "Resonant X-ray emission spectroscopy (RXES) has developed in the past decade as a powerful tool to probe the chemical state of a metal center and in situ study chemical reactions. We have used it to monitor spectral changes associated with the reduction of osmium(VI) nitrido complexes to the osmium(III) ammine state by the biologically relevant reducing agent, glutathione. RXES difference maps are consistent with the proposed DFT mechanism and the formation of two stable osmium(IV) intermediates, thereby supporting the overall pathway for the reduction of these high-valent anticancer metal complexes for which reduction by thiols within cells may be essential to the antiproliferative activity." @default.
- W3154874517 created "2021-04-26" @default.
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- W3154874517 creator A5076475134 @default.
- W3154874517 date "2021-04-19" @default.
- W3154874517 modified "2023-09-27" @default.
- W3154874517 title "Reduction Mechanisms of Anticancer Osmium(VI) Complexes Revealed by Atomic Telemetry and Theoretical Calculations" @default.
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- W3154874517 doi "https://doi.org/10.1021/acs.inorgchem.1c00467" @default.
- W3154874517 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33871984" @default.
- W3154874517 hasPublicationYear "2021" @default.
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