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- W3154989288 abstract "A [3+1+1+1] cycloaddition was developed among 2-arylpropene, ketone and DMSO in the presence of K2S2O8. 2-arylpropene provides three carbons, ketone offers one carbon, and DMSO as dual carbon donor contributes two carbons to the six-membered carbocycle. It gave the cyclohexene motif and spirocyclohexene skeleton. Four C−C bonds formed in this process. Both propylene and ketone could be well tolerated and give the corresponding cyclohexene or spirocyclohexene motif in useful yields. Based on the controlled experiments, a possible mechanism was proposed." @default.
- W3154989288 created "2021-04-26" @default.
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- W3154989288 date "2021-05-06" @default.
- W3154989288 modified "2023-10-02" @default.
- W3154989288 title "Effective [3+1+1+1] Cycloaddition to Six‐Membered Carbocycle Based on DMSO as Dual Carbon Synthon" @default.
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- W3154989288 doi "https://doi.org/10.1002/adsc.202100115" @default.
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