FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3156854278> ?p ?o ?g. }

• W3156854278 endingPage "1896" @default.
• W3156854278 startingPage "1890" @default.
• W3156854278 abstract "Abstract Reduction of 1,2‐bis[(2,6‐dibenzhydryl‐4‐methylphenyl)imino]acenaphthene (Ar BIG ‐bian) with an excess of magnesium in tetrahydrofuran (thf) or with an excess of calcium in 1,2‐dimethoxyethane (dme) and crystallization of the crude products from the reaction mixtures affords monomeric complexes [(Ar BIG ‐bian)Mg(thf) 2 ] ( 1 ) or [(Ar BIG ‐bian)Ca(dme) 2 ] ( 2 ), respectively. Hydrolysis of complex 1 affords metal‐free diamine [Ar BIG ‐bianH 2 (thf)] ( 3 ). Complexes 1 and 2 readily react with CO 2 to form the corresponding carbamates [(Ar BIG ‐bian)(CO 2 ) 2 Mg(thf) 2 ] ( 4 ) and [(Ar BIG ‐bian)(CO 2 ) 2 Ca(dme) 2 ] ( 5 ). Compounds 1 – 5 have been characterized by NMR and IR spectroscopy as well as elemental analysis. The molecular structures of 1 , 2 , 3 , and 5 have been determined by the single crystal X‐ray analysis." @default.
• W3156854278 created "2021-04-26" @default.
• W3156854278 creator A5009120756 @default.
• W3156854278 creator A5009656547 @default.
• W3156854278 creator A5010165289 @default.
• W3156854278 creator A5016298475 @default.
• W3156854278 creator A5056145637 @default.
• W3156854278 creator A5077490946 @default.
• W3156854278 creator A5089972629 @default.
• W3156854278 date "2021-04-08" @default.
• W3156854278 modified "2023-10-17" @default.
• W3156854278 title "Magnesium and Calcium Complexes of Ar ^BIG ‐bian and Their Reactivity towards CO ₂ (Ar ^BIG ‐bian=1,2‐bis[(2,6‐dibenzhydryl‐4‐methylphenyl)imino]acenaphthene)" @default.
• W3156854278 cites W1957314909 @default.
• W3156854278 cites W1968218438 @default.
• W3156854278 cites W1969360633 @default.
• W3156854278 cites W1973423312 @default.
• W3156854278 cites W1980089423 @default.
• W3156854278 cites W1983185816 @default.
• W3156854278 cites W2019594135 @default.
• W3156854278 cites W2022333402 @default.
• W3156854278 cites W2025696697 @default.
• W3156854278 cites W2042093836 @default.
• W3156854278 cites W2051586079 @default.
• W3156854278 cites W2052845800 @default.
• W3156854278 cites W2059205366 @default.
• W3156854278 cites W2060855979 @default.
• W3156854278 cites W2073287143 @default.
• W3156854278 cites W2084826958 @default.
• W3156854278 cites W2087640463 @default.
• W3156854278 cites W2087869506 @default.
• W3156854278 cites W2090056223 @default.
• W3156854278 cites W2095362631 @default.
• W3156854278 cites W2098324669 @default.
• W3156854278 cites W2113339228 @default.
• W3156854278 cites W2132454074 @default.
• W3156854278 cites W2132486002 @default.
• W3156854278 cites W2156757089 @default.
• W3156854278 cites W2163695728 @default.
• W3156854278 cites W2167590372 @default.
• W3156854278 cites W2296880544 @default.
• W3156854278 cites W2322647058 @default.
• W3156854278 cites W2345476069 @default.
• W3156854278 cites W2396997485 @default.
• W3156854278 cites W2555840873 @default.
• W3156854278 cites W2755731014 @default.
• W3156854278 cites W2766871108 @default.
• W3156854278 cites W2771222095 @default.
• W3156854278 cites W2799322354 @default.
• W3156854278 cites W2801409965 @default.
• W3156854278 cites W2803426259 @default.
• W3156854278 cites W2808620441 @default.
• W3156854278 cites W2808901750 @default.
• W3156854278 cites W2823770523 @default.
• W3156854278 cites W2883429641 @default.
• W3156854278 cites W2894848096 @default.
• W3156854278 cites W2900626066 @default.
• W3156854278 cites W2902476412 @default.
• W3156854278 cites W2913208981 @default.
• W3156854278 cites W2924929857 @default.
• W3156854278 cites W2934715593 @default.
• W3156854278 cites W2945424908 @default.
• W3156854278 cites W2950320209 @default.
• W3156854278 cites W2962812409 @default.
• W3156854278 cites W2972110344 @default.
• W3156854278 cites W2974665574 @default.
• W3156854278 cites W3008516988 @default.
• W3156854278 cites W3024748172 @default.
• W3156854278 cites W3042940629 @default.
• W3156854278 cites W3092444637 @default.
• W3156854278 cites W3122509240 @default.
• W3156854278 cites W3133963839 @default.
• W3156854278 cites W4241986113 @default.
• W3156854278 cites W4244615892 @default.
• W3156854278 cites W4377431151 @default.
• W3156854278 doi "https://doi.org/10.1002/ejic.202100179" @default.
• W3156854278 hasPublicationYear "2021" @default.
• W3156854278 type Work @default.
• W3156854278 sameAs 3156854278 @default.
• W3156854278 citedByCount "9" @default.
• W3156854278 countsByYear W31568542782021 @default.
• W3156854278 countsByYear W31568542782022 @default.
• W3156854278 countsByYear W31568542782023 @default.
• W3156854278 crossrefType "journal-article" @default.
• W3156854278 hasAuthorship W3156854278A5009120756 @default.
• W3156854278 hasAuthorship W3156854278A5009656547 @default.
• W3156854278 hasAuthorship W3156854278A5010165289 @default.
• W3156854278 hasAuthorship W3156854278A5016298475 @default.
• W3156854278 hasAuthorship W3156854278A5056145637 @default.
• W3156854278 hasAuthorship W3156854278A5077490946 @default.
• W3156854278 hasAuthorship W3156854278A5089972629 @default.
• W3156854278 hasConcept C142724271 @default.
• W3156854278 hasConcept C147789679 @default.
• W3156854278 hasConcept C155647269 @default.
• W3156854278 hasConcept C17525397 @default.
• W3156854278 hasConcept C178790620 @default.
• W3156854278 hasConcept C179104552 @default.
• W3156854278 hasConcept C185592680 @default.
• W3156854278 hasConcept C204787440 @default.

• next