FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3157266840> ?p ?o ?g. }

• W3157266840 endingPage "123813" @default.
• W3157266840 startingPage "123813" @default.
• W3157266840 abstract "In a groundbreaking study, Akcora group has shown that poly(ethylene oxide), PEO, nanocomposites with dynamically asymmetric, heterogeneous interfaces present a unique and reversible thermal-stiffening behavior above the glass transition temperature of the adsorbed polymer (Senses, E. et al., ACS Appl. Mater. Interfaces 2015, 7, 14682–14689.). However, chemically heterogeneous interfaces can be fragile under severe shear fields that are common in continuous polymer processes. The current study is inspired by the work done in Akcora group on thermally-stiffening polymer nanocomposites and is aimed at understanding the effect of continuous processing operations such as extrusion on the structure and properties of thermally-stiffening nanocomposites. The effect of processing on nanocomposites of PEO and colloidal silica, SiO2, were investigated via thermogravimetric analysis (TGA), scanning electron microscopy (SEM), small and wide angle X-ray scattering, attenuated total reflectance-Fourier transform infrared (ATR-FTIR), and rheometry. Three types of silica nanoparticles were employed in the current study (while keeping the average silica nanoparticle size and concentration constant: 40–50 nm diameter and 30% by weight): bare silica, silica adsorbed with polycarbonate (PC), and silica adsorbed with poly(2–vinyl pyridine), P2VP. The adsorption of PC and P2VP onto silica creates a dynamically asymmetric, heterogeneous interface that is quite different compared to homogeneous interfaces where either nanoparticle surfaces are chemically modified with small chemical groups or with long grafted chains. The results indicated that upon extrusion, the average size of secondary agglomerates either remained unchanged or decreased slightly but the amount of agglomeration increased leading to deterioration of silica nanoparticle dispersion and viscoelastic properties (at temperatures below the glass transition temperature of the adsorbed polymer). Among the three systems studied, P2VP-adsorbed silica containing samples showed the largest degradation of viscoelastic properties upon extrusion, which was attributed to the desorption and disentanglement within the heterogeneous interface or to agglomeration leading to breaking of the percolated structure formed by nanoparticles and polymer bridges." @default.
• W3157266840 created "2021-05-10" @default.
• W3157266840 creator A5008009682 @default.
• W3157266840 creator A5044051665 @default.
• W3157266840 creator A5064024276 @default.
• W3157266840 creator A5082454483 @default.
• W3157266840 creator A5086221340 @default.
• W3157266840 date "2021-06-01" @default.
• W3157266840 modified "2023-10-17" @default.
• W3157266840 title "Stability of particle dispersion and heterogeneous interfacial layers in polymer nanocomposites" @default.
• W3157266840 cites W1968577620 @default.
• W3157266840 cites W1975834815 @default.
• W3157266840 cites W1981876390 @default.
• W3157266840 cites W1984428359 @default.
• W3157266840 cites W1989275496 @default.
• W3157266840 cites W2008342341 @default.
• W3157266840 cites W2026534098 @default.
• W3157266840 cites W2031635950 @default.
• W3157266840 cites W2038340187 @default.
• W3157266840 cites W2040124111 @default.
• W3157266840 cites W2045566611 @default.
• W3157266840 cites W2057466869 @default.
• W3157266840 cites W2064403993 @default.
• W3157266840 cites W2067263629 @default.
• W3157266840 cites W2072604688 @default.
• W3157266840 cites W2078212425 @default.
• W3157266840 cites W2079079268 @default.
• W3157266840 cites W2079913092 @default.
• W3157266840 cites W2085506072 @default.
• W3157266840 cites W2088697330 @default.
• W3157266840 cites W2089355120 @default.
• W3157266840 cites W2092706511 @default.
• W3157266840 cites W2103058354 @default.
• W3157266840 cites W2103212187 @default.
• W3157266840 cites W2140551148 @default.
• W3157266840 cites W2152956366 @default.
• W3157266840 cites W2166831746 @default.
• W3157266840 cites W2220778242 @default.
• W3157266840 cites W2271867996 @default.
• W3157266840 cites W2290517140 @default.
• W3157266840 cites W2313793833 @default.
• W3157266840 cites W2314294626 @default.
• W3157266840 cites W2324024561 @default.
• W3157266840 cites W2324975076 @default.
• W3157266840 cites W2325806896 @default.
• W3157266840 cites W2331563203 @default.
• W3157266840 cites W2339538625 @default.
• W3157266840 cites W2400424484 @default.
• W3157266840 cites W2468794281 @default.
• W3157266840 cites W2483654653 @default.
• W3157266840 cites W2520790534 @default.
• W3157266840 cites W2522438847 @default.
• W3157266840 cites W2580910706 @default.
• W3157266840 cites W2787597958 @default.
• W3157266840 cites W2789913922 @default.
• W3157266840 cites W2804628133 @default.
• W3157266840 cites W2898326545 @default.
• W3157266840 cites W2991274937 @default.
• W3157266840 cites W3094931225 @default.
• W3157266840 cites W3102024575 @default.
• W3157266840 cites W3106109655 @default.
• W3157266840 doi "https://doi.org/10.1016/j.polymer.2021.123813" @default.
• W3157266840 hasPublicationYear "2021" @default.
• W3157266840 type Work @default.
• W3157266840 sameAs 3157266840 @default.
• W3157266840 citedByCount "2" @default.
• W3157266840 countsByYear W31572668402023 @default.
• W3157266840 crossrefType "journal-article" @default.
• W3157266840 hasAuthorship W3157266840A5008009682 @default.
• W3157266840 hasAuthorship W3157266840A5044051665 @default.
• W3157266840 hasAuthorship W3157266840A5064024276 @default.
• W3157266840 hasAuthorship W3157266840A5082454483 @default.
• W3157266840 hasAuthorship W3157266840A5086221340 @default.
• W3157266840 hasBestOaLocation W31572668401 @default.
• W3157266840 hasConcept C127413603 @default.
• W3157266840 hasConcept C14631669 @default.
• W3157266840 hasConcept C148328677 @default.
• W3157266840 hasConcept C150394285 @default.
• W3157266840 hasConcept C155672457 @default.
• W3157266840 hasConcept C159985019 @default.
• W3157266840 hasConcept C171250308 @default.
• W3157266840 hasConcept C178790620 @default.
• W3157266840 hasConcept C185592680 @default.
• W3157266840 hasConcept C188027245 @default.
• W3157266840 hasConcept C192562407 @default.
• W3157266840 hasConcept C3231350 @default.
• W3157266840 hasConcept C42360764 @default.
• W3157266840 hasConcept C521977710 @default.
• W3157266840 hasConcept C59061564 @default.
• W3157266840 hasConcept C60100273 @default.
• W3157266840 hasConcept C92880739 @default.
• W3157266840 hasConceptScore W3157266840C127413603 @default.
• W3157266840 hasConceptScore W3157266840C14631669 @default.
• W3157266840 hasConceptScore W3157266840C148328677 @default.
• W3157266840 hasConceptScore W3157266840C150394285 @default.
• W3157266840 hasConceptScore W3157266840C155672457 @default.
• W3157266840 hasConceptScore W3157266840C159985019 @default.
• W3157266840 hasConceptScore W3157266840C171250308 @default.

• next