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• W3157337487 endingPage "116113" @default.
• W3157337487 startingPage "116113" @default.
• W3157337487 abstract "The present work deals with a measurement system for densities of compressed liquids over the temperature range of 263–473 K and pressure up to 70 MPa. The functionality of the installation is based on the usage of a commercial vibrating tube densimeter DMA HP. Calibration of the DMA HP cell was performed by two methods in which a vacuum, water, toluene, and aqueous solution of NaCl were used as calibration fluids. The density at high pressures of 2-pyrrolidone was measured in the range of 0.1–70 MPa at two different temperatures (308.15 and 323.15) K, and that of water-2-pyrrolidone mixture was measured in the entire composition range of the mixture liquid state in the range of 0.1–70 MPa at five different temperatures - from (278.15 to 323.15) K. Density data were fitted by Tait-type equation where the absolute average percentage deviation between measured and calculated densities was about 0.02%. These data were later used to calculate the excess molar volumes, VmE, partial molar volumes of water, V1 and 2-pyrrolidone V2, and to obtain the limiting partial molar volumes of components Vi∞. Structure–property relationships were analyzed, the effects of temperature and pressure on these properties were also discussed." @default.
• W3157337487 created "2021-05-10" @default.
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• W3157337487 date "2021-08-01" @default.
• W3157337487 modified "2023-09-24" @default.
• W3157337487 title "Density of water - 2-pyrrolidone mixture a new vibrating tube densimeter from (278.15–323.15) K and up to 70 MPa" @default.
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• W3157337487 doi "https://doi.org/10.1016/j.molliq.2021.116113" @default.
• W3157337487 hasPublicationYear "2021" @default.
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