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- W3157421750 abstract "Abstract Effective utilization of Li‐metal electrodes is vital for maximizing the specific energy of lithium–oxygen (Li–O 2 ) batteries. Many conventional electrolytes that support Li–O 2 cathode processes (e.g. , dimethyl sulfoxide, DMSO) are incompatible with Li‐metal. Here, a wide range of ternary solutions based on solvent, salt, and ionic liquid (IL) are explored to understand how formulations may be tailored to enhance stability and performance of DMSO at Li‐metal electrodes. The optimized formulations therein facilitate stable Li plating/stripping performances, Columbic efficiencies >94%, and improved performance in Li–O 2 full cells. Characterization of Li surfaces reveals the suppression of dendritic deposition and corrosion and the modulation of decomposition reactions at the interface within optimized formulations. These observations are correlated with spectroscopic characterization and simulation of local solvation environments, indicating the persistent importance of DMSO–Li + ‐cation interactions. Therein, stabilization remains dependent on important molar ratios in solution and the 4:1 solvent‐salt ratio, corresponding to ideal coordination spheres in these systems, is revealed as critical for these ternary formulations. Importantly, introducing this stable, non‐volatile IL has negligible disrupting effects on the critical stabilizing interactions between Li + and DMSO and, thus, may be carefully introduced to tailor other key electrolyte properties for Li–O 2 cells." @default.
- W3157421750 created "2021-05-10" @default.
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- W3157421750 date "2021-05-04" @default.
- W3157421750 modified "2023-09-27" @default.
- W3157421750 title "Design Parameters for Ionic Liquid–Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li–O <sub>2</sub> Batteries" @default.
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- W3157421750 cites W1984060337 @default.
- W3157421750 cites W1987452691 @default.
- W3157421750 cites W2007490170 @default.
- W3157421750 cites W2007739424 @default.
- W3157421750 cites W2017646729 @default.
- W3157421750 cites W2019619536 @default.
- W3157421750 cites W2025561598 @default.
- W3157421750 cites W2030087742 @default.
- W3157421750 cites W2035537551 @default.
- W3157421750 cites W2042246080 @default.
- W3157421750 cites W2043473097 @default.
- W3157421750 cites W2047775546 @default.
- W3157421750 cites W2061253553 @default.
- W3157421750 cites W2062710357 @default.
- W3157421750 cites W2066015753 @default.
- W3157421750 cites W2069765442 @default.
- W3157421750 cites W2093126459 @default.
- W3157421750 cites W2126323174 @default.
- W3157421750 cites W2146639505 @default.
- W3157421750 cites W2154898558 @default.
- W3157421750 cites W2155489103 @default.
- W3157421750 cites W2265160803 @default.
- W3157421750 cites W2289183488 @default.
- W3157421750 cites W2289576600 @default.
- W3157421750 cites W2298381422 @default.
- W3157421750 cites W2314013757 @default.
- W3157421750 cites W2315779695 @default.
- W3157421750 cites W2315940645 @default.
- W3157421750 cites W2318536044 @default.
- W3157421750 cites W2326574296 @default.
- W3157421750 cites W2337775354 @default.
- W3157421750 cites W2340967682 @default.
- W3157421750 cites W2414193723 @default.
- W3157421750 cites W2429337228 @default.
- W3157421750 cites W2507174348 @default.
- W3157421750 cites W2510611986 @default.
- W3157421750 cites W2522398691 @default.
- W3157421750 cites W2527472235 @default.
- W3157421750 cites W2537566083 @default.
- W3157421750 cites W2537935631 @default.
- W3157421750 cites W2547406798 @default.
- W3157421750 cites W2549046185 @default.
- W3157421750 cites W2566193132 @default.
- W3157421750 cites W2579562509 @default.
- W3157421750 cites W2594710505 @default.
- W3157421750 cites W2595347209 @default.
- W3157421750 cites W2602657889 @default.
- W3157421750 cites W2606032947 @default.
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- W3157421750 cites W2763902109 @default.
- W3157421750 cites W2772904049 @default.
- W3157421750 cites W2774731903 @default.
- W3157421750 cites W2780948826 @default.
- W3157421750 cites W2782177728 @default.
- W3157421750 cites W2805429523 @default.
- W3157421750 cites W2841944325 @default.
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- W3157421750 doi "https://doi.org/10.1002/adfm.202010627" @default.
- W3157421750 hasPublicationYear "2021" @default.
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