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- W3157721522 abstract "This study presents a novel and facile strategy for fabricating fire-resistant, ultraviolet (UV)-shielding, and tensile-enhanced polylactide (PLA) composites using two-dimensional (2D) MXene (Ti3C2) flakes chemically modified with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO). The thermal and burning performances of PLA composites were demonstrated by the limiting oxygen index, UL-94 test, and cone calorimetry. The UV-shielding and tensile performances were also examined. The results revealed that PLA/Ti3C2–DOPO (3 wt %) displayed a V-0 rating in the UL-94 test. The enhancement against fire hazard was reflected by the significant reduction in the peak heat release rate (33.7%), total heat release (47%), peak CO production (58.8%), and total smoke production (41.7%). The improved fire-safety performance of the composites is attributed to the interplay of catalytic, barrier, and condensed effects of the Ti3C2–DOPO nanosheets in the PLA matrix. PLA/Ti3C2–DOPO also showed an increase (∼9%) in tensile strength and an “Excellent” level (UPF 50+) in the UV-protection assessment. In all, this study introduces a novel chemical modification strategy for 2D MXene flakes to fabricate multifunctional PLA composites, which are promising candidates for next-generation sustainable and protective plastic products." @default.
- W3157721522 created "2021-05-10" @default.
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- W3157721522 date "2021-05-03" @default.
- W3157721522 modified "2023-10-16" @default.
- W3157721522 title "DOPO-Decorated Two-Dimensional MXene Nanosheets for Flame-Retardant, Ultraviolet-Protective, and Reinforced Polylactide Composites" @default.
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- W3157721522 doi "https://doi.org/10.1021/acsami.1c05587" @default.
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