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- W315794277 abstract "In the title salt co-crystal, [Ag(C6H5N2O)(C6H6N2O)]ClO4·[Ag(C6H6N2O)2], the asymmetric unit comprises a [Ag(LH)2]+ cation, a perchlorate anion and a neutral (LH)AgL molecule, where LH is pyridine-2-carboxaldoxime. Both silver-containing species feature N,N′-chelating LH and L ligands, which define an N4 donor set that is highly distorted [dihedral angles between AgC2N2 chelate rings = 45.7 (3) and 44.3 (2)°, respectively] owing, in part, to the close approach of a neighbouring Ag atom, leading to an argentophilic interaction [Ag⋯Ag = 3.1868 (11) Å]. The molecular conformations are stabilized by intramolecular O—H⋯O hydrogen bonds. In the crystal, O—H⋯O interactions lead to supramolecular chains along [010]. Chains aggregate into layers in the ab plane, defining channels along [100] in which reside the perchlorate anions; the latter are disordered over two overlapped orientations in a 50:50 ratio." @default.
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- W315794277 date "2012-04-21" @default.
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- W315794277 title "[(<i>E</i>)-Oxido(pyridin-2-ylmethylidene)amine-κ<sup>2</sup><i>N</i>,<i>N</i>′][(<i>E</i>)-<i>N</i>-(pyridin-2-ylmethylidene)hydroxylamine-κ<sup>2</sup><i>N</i>,<i>N</i>′]silver(I) perchlorate–bis[(<i>E</i>)-<i>N</i>-(pyridin-2-ylmethylidene)hydroxylamine-κ<sup>2</sup><i>N</i>,<i>N</i>′]silver(I) (1/1)" @default.
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- W315794277 doi "https://doi.org/10.1107/s160053681201625x" @default.
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