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- W3157985392 abstract "A facile method to synthesize dual phase Li4Ti5O12-TiO2 nanowires and their performance as anode material for lithium-ion battery are investigated. Li4Ti5O12-TiO2 nanowires are obtained from titanium nanoparticles by applying the wet corrosion process for the nanostructure formation and subsequent ion exchange processes. Post-heat treatments are adopted to tune the mixed phase composition of the nanowires, which significantly influences the electrochemical performance. The dual phase nanowires-based anode materials with a TiO2: Li4Ti5O12 phase ratio of 7:3 exhibit the highest delithiation capacity of 180 mAh/g and 105 mAh/g at 0.5 C and 5 C, respectively. In addition, it shows a remarkable capacity retention of ~95% after 150 cycles at 5 C, which is a significant improvement compared to previous reports on Li4Ti5O12-TiO2 based anode materials synthesized at low temperatures. This dual phase anode material based on Li4Ti5O12-TiO2 nanowires combines two advantages: i) High aspect ratio nanostructures increase the surface area and shorten the diffusion path of lithium ions and ii) the dual phase accelerates ion/electron migration owing to abundant interfaces/grain boundaries. Consequently, the proposed synthesis route for Li4Ti5O12-TiO2 nanowires provides an effective and highly reproducible approach to fabricate dual phase Li4Ti5O12-TiO2 nanowires as anode materials for lithium ion batteries." @default.
- W3157985392 created "2021-05-10" @default.
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- W3157985392 date "2021-09-01" @default.
- W3157985392 modified "2023-10-17" @default.
- W3157985392 title "Facile synthesis of dual-phase lithium titanate nanowires as anode materials for lithium-ion battery" @default.
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- W3157985392 doi "https://doi.org/10.1016/j.jallcom.2021.160038" @default.
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