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• W3158207959 abstract "An effect of using different TiO2 polymorphs as support for H3PW12O40 heteropolyacid on the (photo)catalytic performance of the H3PW12O40/TiO2 catalyst was investigated. Two kinds of synthesis methods of the catalysts have been applied. In the first, the H3PW12O40/TiO2 catalyst was prepared by impregnation of either the pure anatase (A), or rutile (R), or a mixture of the two (P25) in a solution of H3PW12O40. In the second method, an additional pre-treatment is being applied to all three types of support, A, R and P25, consisting of hydrothermal sonication with KOH solution. The catalysts and supports were characterized by XRD, SEM, BET analysis and FTIR spectroscopy. Catalytic tests show that H3PW12O40/P25 catalyst exhibits a higher (photo)activity to n-butanol dehydration in gas phase compared to the catalysts supported on either of pure polymorphs and that the sonication pre-treatment did not improve the activity of the catalysts so prepared. The application of the not treated P25 - the mixture of anatase and rutile as the support of heteropolyacid allowed to find the efficient heterogeneous catalyst." @default.
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• W3158207959 date "2021-11-01" @default.
• W3158207959 modified "2023-10-14" @default.
• W3158207959 title "The role of TiO2 polymorphs as support for the Keggin-type tungstophosphoric heteropolyacid as catalysts for n-butanol dehydration" @default.
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• W3158207959 doi "https://doi.org/10.1016/j.cattod.2021.04.021" @default.
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