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- W3158385191 abstract "Two ternary antimony-chalcogenides of Cs4Sb4S8 (1) and Cs3Sb5Se9 (2), were synthesized in organic solvent under solvothermal conditions. Single-crystal X-ray diffraction analyses showed that compound 1 is characterized by an infinite [Sb2S8]n4n− chain formed by the alternating connection of two [Sb(1)S3] pyramidal and two [Sb(2)S4] tetrahedral. In compound 2, the [Sb2Se5]n4n− chain is interconnected by the two octahedral [Sb(3)Se6] units via corner-sharing, and the [Sb3Se5]− ribbon is interconnected by two [Sb2Se5]n4n− chains and pyramidal [Sb(5)Se3] unit via corner-sharing, finally, the[Sb5Se9]n3n− layer interconnected by [Sb3Se5]− ribbon and [Sb2Se5] dimer via corner-sharing. As estimated from the solid-state absorption spectra, the band gaps of 1 and 2 are 2.11 and 1.54 eV, respectively." @default.
- W3158385191 created "2021-05-10" @default.
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- W3158385191 date "2021-07-01" @default.
- W3158385191 modified "2023-09-24" @default.
- W3158385191 title "Two ternary antimony-chalcogenides of Cs4Sb4S8 and Cs3Sb5Se9" @default.
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- W3158385191 doi "https://doi.org/10.1016/j.inoche.2021.108635" @default.
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