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• W3158538081 abstract "The direct C–H activation without directing groups can realize the para-selectivity, which is a powerful and concise approach for functionalization of arenes. Utilizing the strategy, a C5-olefination of methyleneindolinones has been successfully developed by palladium-catalyzed direct C–H activation, which provides an expeditious access to 5-vinylindolin-2-ones with high regioselectivity. The protocol is distinguished by a mild reaction system avoiding ligand and high temperature. The kinetic isotope experiments indicate that the C–H bond cleavage is the rate-limiting step." @default.
• W3158538081 created "2021-05-10" @default.
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• W3158538081 date "2021-05-06" @default.
• W3158538081 modified "2023-10-14" @default.
• W3158538081 title "Pd-Catalyzed Direct C–H Activation for the C5-Olefination of Methyleneindolinones" @default.
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• W3158538081 doi "https://doi.org/10.1021/acs.joc.1c00637" @default.
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