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- W3159132387 abstract "A chiral phosphoric acid-catalyzed kinetic resolution of tertiary allylic alcohols was developed to provide structurally valuable enantioenriched 2,2-disubstituted tetrahydrofurans, tetrahydropyrans, and oxepane. A variety of tertiary allylic alcohols were resolved with selectivity factors of ≤120. A tertiary allylic carbocationic intermediate mediates the enantioselective intramolecular substitution to achieve high regio- and enantioselectivity. A gram-scale reaction with low catalyst loading and subsequent transformations of the recovered alcohols and products demonstrated the utility of this method." @default.
- W3159132387 created "2021-05-10" @default.
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- W3159132387 date "2021-04-30" @default.
- W3159132387 modified "2023-10-07" @default.
- W3159132387 title "Kinetic Resolution of Tertiary Allylic Alcohols: Highly Enantioselective Access to Cyclic Ethers Bearing an α-Tetrasubstituted Stereocenter" @default.
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- W3159132387 doi "https://doi.org/10.1021/acs.orglett.1c01110" @default.
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