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- W3159217721 abstract "In this work, the influence of orientation and structural peculiarities on the radiation-induced oxidation/crosslinking changes in different polyethylenes (PEs) was studied. For that reason, low density polyethylene (LDPE), linear low density polyethylene (LLDPE) and high density polyethylene (HDPE) were oriented via solid-state stretching at elevated temperature up to draw ratio λ=15. Later on, oriented samples were gamma-irradiated to various absorbed doses (up to 700 kGy), in air at room temperature, at a dose rate of 9 KGy/h. Differential scanning calorimetry (DSC), IR spectroscopy and gel measurements were used to determine changes in crystallinity, oxidative degradation and degree of network formation, respectively. Conclusions derived according to these methods were compared. The differences in crystallinity, oxidation and gel content behavior are caused primarily by the structural peculiarities of different types of PEs, heterogeneous nature of radiation effects in semicrystalline polymers and, in the case of oriented samples, by the molecular orientation as well. Presented results reveal complicate crosslinking behavior with orientation while increase/decrease in crystallinity/oxidation with draw ratio was clearly evident." @default.
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- W3159217721 date "2008-01-01" @default.
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- W3159217721 title "The influence of orientation on the radiation-induced crosslinking/oxidative behavior of different PEs" @default.
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