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- W3159458577 abstract "Following the pattern: The Au-catalyzed formal dehydro-Diels-Alder reaction of enynamide-yne derivatives was shown experimentally and computationally to proceed according to a dual gold-catalyzed mechanism. The reaction proceeded in 3 stages: initial formation of a σ,π-digold complex followed by cyclization to produce a gem-diaurated aryl complex and finally a catalyst transfer. The concerted or stepwise nature of the cyclization event was found to depend on the substitution pattern of the ynamide moiety." @default.
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- W3159458577 date "2021-05-27" @default.
- W3159458577 modified "2023-09-24" @default.
- W3159458577 title "On the Mechanism of Au‐Catalyzed Enynamide‐yne Dehydro‐Diels‐Alder Reactions: An Experimental and Computational Study" @default.
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- W3159458577 doi "https://doi.org/10.1002/chem.202100580" @default.
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