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- W31596692 abstract "The reaction of the potentially tridentate phosphinite PCP pincer type ligand [C6H4-1,3-(OPPh2)2] with [(η6-p-cymene)RuCl2]2 affords the bimetallic species [C6H4-1,3-(OPPh2{Ru(η6-p-cymene)Cl2})2]. Several attempts, including the change of the ruthenium starting material (e.g. [(η6-benzene)RuCl2]2) and reflux conditions to achieve the coordination of the diphosphinite [C6H4-1,3-(OPPh2)2] in a tridentate PCP pincer fashion failed. Complex [C6H4-1,3-(OPPh2{Ru(η6-p-cymene)Cl2})2] was tested in the transfer hydrogenation of ketones." @default.
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- W31596692 date "2006-03-01" @default.
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- W31596692 title "Ketone transfer hydrogenation reactions catalyzed by a phosphinite ruthenium PCP complex" @default.
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- W31596692 doi "https://doi.org/10.1016/j.molcata.2005.11.041" @default.
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