Matches in SemOpenAlex for { <https://semopenalex.org/work/W3159691015> ?p ?o ?g. }
- W3159691015 endingPage "1477" @default.
- W3159691015 startingPage "1468" @default.
- W3159691015 abstract "Seed-assisted low alkalinity gel system was developed to explore the organic-free synthesis of MOR zeolite. MOR nanoassemblies with Si/Al ratio (SAR) up to 9.4 and high solid yield (84–94%) were successfully obtained under controlled low alkalinity conditions. Characterization results demonstrate that the acid strength increases in parallel with the SAR, while the total acid amount and the proton distribution in the main channels and the side pockets are similar for the samples. The proton distribution in the H-MOR is not straightforwardly related to the Na+ distribution in the as-synthesized MOR, implying the transfer of the protons among the oxygen sites of framework T atom. Relative to low-silica samples I-5.3 and I-7.4, sample I-9.4 displays the best mass transfer performance and accessibility of the acid sites by pyridine due to its relatively low Al density and mild dealumination degree. Correspondingly, sample I-9.4 (pyridine-modified catalyst) shows the best activity with ca. 100% selectivity of methyl acetate (MAc) in the DME carbonylation reaction. The high steady MAc yield (6.8 mmol/g/h) over sample I-9.4 suggests the promising application of MOR nanoassemblies synthesized by this economical organic-free strategy" @default.
- W3159691015 created "2021-05-10" @default.
- W3159691015 creator A5006920472 @default.
- W3159691015 creator A5014923308 @default.
- W3159691015 creator A5030199923 @default.
- W3159691015 creator A5035354470 @default.
- W3159691015 creator A5040573133 @default.
- W3159691015 creator A5045150842 @default.
- W3159691015 creator A5057015233 @default.
- W3159691015 creator A5066328432 @default.
- W3159691015 creator A5067834684 @default.
- W3159691015 creator A5081372502 @default.
- W3159691015 date "2021-09-01" @default.
- W3159691015 modified "2023-10-16" @default.
- W3159691015 title "Organic-free synthesis of MOR nanoassemblies with excellent DME carbonylation performance" @default.
- W3159691015 cites W1576658951 @default.
- W3159691015 cites W1963746224 @default.
- W3159691015 cites W1965722781 @default.
- W3159691015 cites W1965731502 @default.
- W3159691015 cites W1966891821 @default.
- W3159691015 cites W1972465386 @default.
- W3159691015 cites W1976538092 @default.
- W3159691015 cites W1977674479 @default.
- W3159691015 cites W1978117706 @default.
- W3159691015 cites W1979731689 @default.
- W3159691015 cites W1984111505 @default.
- W3159691015 cites W1986463827 @default.
- W3159691015 cites W198927204 @default.
- W3159691015 cites W1991009486 @default.
- W3159691015 cites W1991629859 @default.
- W3159691015 cites W1995624706 @default.
- W3159691015 cites W2001078114 @default.
- W3159691015 cites W2007045518 @default.
- W3159691015 cites W2013262265 @default.
- W3159691015 cites W2019265654 @default.
- W3159691015 cites W2021311510 @default.
- W3159691015 cites W2026405532 @default.
- W3159691015 cites W2030457214 @default.
- W3159691015 cites W2032340271 @default.
- W3159691015 cites W2040240613 @default.
- W3159691015 cites W2050691986 @default.
- W3159691015 cites W2054030141 @default.
- W3159691015 cites W2063150156 @default.
- W3159691015 cites W2092440525 @default.
- W3159691015 cites W2095974533 @default.
- W3159691015 cites W2135618216 @default.
- W3159691015 cites W2143076240 @default.
- W3159691015 cites W2145328429 @default.
- W3159691015 cites W2160098490 @default.
- W3159691015 cites W2168516909 @default.
- W3159691015 cites W2323051734 @default.
- W3159691015 cites W2328413555 @default.
- W3159691015 cites W2330282048 @default.
- W3159691015 cites W2467601336 @default.
- W3159691015 cites W2581069877 @default.
- W3159691015 cites W2607098769 @default.
- W3159691015 cites W2737530672 @default.
- W3159691015 cites W2752970272 @default.
- W3159691015 cites W2807555332 @default.
- W3159691015 cites W2807734441 @default.
- W3159691015 cites W2885862456 @default.
- W3159691015 cites W2886367561 @default.
- W3159691015 cites W2887593491 @default.
- W3159691015 cites W2888783770 @default.
- W3159691015 cites W2902930103 @default.
- W3159691015 cites W2906907671 @default.
- W3159691015 cites W2909111847 @default.
- W3159691015 cites W2912405345 @default.
- W3159691015 cites W2948767299 @default.
- W3159691015 cites W2951270315 @default.
- W3159691015 cites W2976569802 @default.
- W3159691015 cites W2990798500 @default.
- W3159691015 cites W2994265644 @default.
- W3159691015 cites W2999819224 @default.
- W3159691015 cites W3006650198 @default.
- W3159691015 cites W3023748081 @default.
- W3159691015 cites W4237821498 @default.
- W3159691015 cites W4239018782 @default.
- W3159691015 cites W4376596340 @default.
- W3159691015 doi "https://doi.org/10.1016/s1872-2067(20)63777-9" @default.
- W3159691015 hasPublicationYear "2021" @default.
- W3159691015 type Work @default.
- W3159691015 sameAs 3159691015 @default.
- W3159691015 citedByCount "15" @default.
- W3159691015 countsByYear W31596910152021 @default.
- W3159691015 countsByYear W31596910152022 @default.
- W3159691015 countsByYear W31596910152023 @default.
- W3159691015 crossrefType "journal-article" @default.
- W3159691015 hasAuthorship W3159691015A5006920472 @default.
- W3159691015 hasAuthorship W3159691015A5014923308 @default.
- W3159691015 hasAuthorship W3159691015A5030199923 @default.
- W3159691015 hasAuthorship W3159691015A5035354470 @default.
- W3159691015 hasAuthorship W3159691015A5040573133 @default.
- W3159691015 hasAuthorship W3159691015A5045150842 @default.
- W3159691015 hasAuthorship W3159691015A5057015233 @default.
- W3159691015 hasAuthorship W3159691015A5066328432 @default.
- W3159691015 hasAuthorship W3159691015A5067834684 @default.
- W3159691015 hasAuthorship W3159691015A5081372502 @default.