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- W3159737992 abstract "The iminosugar core of natural glyphaeaside C, originally assigned as a derivative of the piperidine natural product 1-deoxynojirimycin (DNJ), has been revised as a derivative of 2,5-dideoxy-2,5-imino-l-mannitol (l-DMDP) by the total synthesis of its enantiomer. This revised l-DMDP-derived configuration is the first of its kind to be observed in nature. The prepared iminosugars displayed the nanomolar inhibition of bovine liver β-glucosidase and β-galactosidase." @default.
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- W3159737992 date "2021-04-30" @default.
- W3159737992 modified "2023-09-27" @default.
- W3159737992 title "Synthesis and Structural Revision of Glyphaeaside C" @default.
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- W3159737992 doi "https://doi.org/10.1021/acs.orglett.1c01248" @default.
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