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• W3159818661 abstract "This work focuses on the development of a responsive sponge made of an anionic cellulose nanocrystal (CNC) skeleton that is electrostatically crosslinked by a pH-responsive poly(allylamine hydrochloride) (PAH) and poly(acrylic acid) (PAA) polyelectrolyte complex (PEC). The results prove the formation of a global percolated network comprised of disordered CNC rods crosslinked by PEC clusters. The bulk density of the freeze-dried CNC-PEC sponges increases from 35 to 93 mg/cm3 with PEC concentration, while the compression modulus of dry specimens increases from 7 up to 62 kPa. At the lowest PEC concentration of 1 wt%, at pH 2.0, the compression modulus decreases to 0.9 kPa, whereas at pH 5.5, it increases to 42 kPa. The intensive complexation between sponge constituents is also reflected in a reduced ability to bind charged dyes at neutral pH values. Decreasing the pH results in an increased adsorption efficiency for anionic dyes, while raising the pH improves the cationic dye adsorption." @default.
• W3159818661 created "2021-05-10" @default.
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• W3159818661 date "2021-08-01" @default.
• W3159818661 modified "2023-10-18" @default.
• W3159818661 title "Electrostatically crosslinked cellulose nanocrystal and polyelectrolyte complex sponges with pH responsiveness" @default.
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• W3159818661 doi "https://doi.org/10.1016/j.carbpol.2021.118131" @default.
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