Matches in SemOpenAlex for { <https://semopenalex.org/work/W3159995379> ?p ?o ?g. }
- W3159995379 abstract "Abstract The living supramolecular polymerization technique provides an exciting research avenue. However, in comparison with the thermodynamic spontaneous nucleation, using simple monomers to realize living supramolecular polymerization is hardly possible from an energy principle. This is because the activation barrier of kinetically trapped simple monomer (nucleation step) is insufficiently high to control the kinetics of subsequent elongation. Here, with the benefit of the confinement from the layered double hydroxide (LDH) nanomaterial, various simple monomers, (such as benzene, naphthalene and pyrene derivatives) successfully form living supramolecular polymer (LSP) with length control and narrow dispersity. The degree of polymerization can reach ~6000. Kinetics studies reveal LDH overcomes a huge energy barrier to inhibit undesired spontaneous nucleation of monomers and disassembly of metastable states. The universality of this strategy will usher exploration into other multifunctional molecules and promote the development of functional LSP." @default.
- W3159995379 created "2021-05-24" @default.
- W3159995379 creator A5033474784 @default.
- W3159995379 creator A5047417329 @default.
- W3159995379 creator A5050029948 @default.
- W3159995379 creator A5051368946 @default.
- W3159995379 date "2021-05-10" @default.
- W3159995379 modified "2023-10-16" @default.
- W3159995379 title "Oriented arrangement of simple monomers enabled by confinement: towards living supramolecular polymerization" @default.
- W3159995379 cites W1495374002 @default.
- W3159995379 cites W1521775498 @default.
- W3159995379 cites W1930369548 @default.
- W3159995379 cites W1953898736 @default.
- W3159995379 cites W1967453978 @default.
- W3159995379 cites W1994486848 @default.
- W3159995379 cites W2003812196 @default.
- W3159995379 cites W2014041614 @default.
- W3159995379 cites W2014182208 @default.
- W3159995379 cites W2014216299 @default.
- W3159995379 cites W2026829672 @default.
- W3159995379 cites W2027685213 @default.
- W3159995379 cites W2029571739 @default.
- W3159995379 cites W2029750840 @default.
- W3159995379 cites W2038567799 @default.
- W3159995379 cites W2068777110 @default.
- W3159995379 cites W2089644153 @default.
- W3159995379 cites W2096966529 @default.
- W3159995379 cites W2103395305 @default.
- W3159995379 cites W2104814249 @default.
- W3159995379 cites W2146669582 @default.
- W3159995379 cites W2172591732 @default.
- W3159995379 cites W2265933344 @default.
- W3159995379 cites W2268742660 @default.
- W3159995379 cites W2304497616 @default.
- W3159995379 cites W2330862899 @default.
- W3159995379 cites W2334086406 @default.
- W3159995379 cites W2338444201 @default.
- W3159995379 cites W2468968368 @default.
- W3159995379 cites W2488265216 @default.
- W3159995379 cites W2560663286 @default.
- W3159995379 cites W2561239809 @default.
- W3159995379 cites W2598224385 @default.
- W3159995379 cites W2612941119 @default.
- W3159995379 cites W2745739596 @default.
- W3159995379 cites W2760922219 @default.
- W3159995379 cites W2765512703 @default.
- W3159995379 cites W2767164365 @default.
- W3159995379 cites W2768471315 @default.
- W3159995379 cites W2769896756 @default.
- W3159995379 cites W2776877381 @default.
- W3159995379 cites W2785471146 @default.
- W3159995379 cites W2795177879 @default.
- W3159995379 cites W2802251241 @default.
- W3159995379 cites W2885012149 @default.
- W3159995379 cites W2900011363 @default.
- W3159995379 cites W2900341012 @default.
- W3159995379 cites W2911270378 @default.
- W3159995379 cites W2915951238 @default.
- W3159995379 cites W2941499520 @default.
- W3159995379 cites W2949057153 @default.
- W3159995379 cites W2953604487 @default.
- W3159995379 cites W2958787945 @default.
- W3159995379 cites W2977888252 @default.
- W3159995379 cites W2992470804 @default.
- W3159995379 cites W2995281348 @default.
- W3159995379 cites W3000014058 @default.
- W3159995379 cites W3005253323 @default.
- W3159995379 cites W3013443679 @default.
- W3159995379 cites W3023673177 @default.
- W3159995379 cites W3025583164 @default.
- W3159995379 cites W3045860514 @default.
- W3159995379 doi "https://doi.org/10.1038/s41467-021-22827-4" @default.
- W3159995379 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8110532" @default.
- W3159995379 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33972542" @default.
- W3159995379 hasPublicationYear "2021" @default.
- W3159995379 type Work @default.
- W3159995379 sameAs 3159995379 @default.
- W3159995379 citedByCount "9" @default.
- W3159995379 countsByYear W31599953792022 @default.
- W3159995379 countsByYear W31599953792023 @default.
- W3159995379 crossrefType "journal-article" @default.
- W3159995379 hasAuthorship W3159995379A5033474784 @default.
- W3159995379 hasAuthorship W3159995379A5047417329 @default.
- W3159995379 hasAuthorship W3159995379A5050029948 @default.
- W3159995379 hasAuthorship W3159995379A5051368946 @default.
- W3159995379 hasBestOaLocation W31599953791 @default.
- W3159995379 hasConcept C11432220 @default.
- W3159995379 hasConcept C127413603 @default.
- W3159995379 hasConcept C130929614 @default.
- W3159995379 hasConcept C166940927 @default.
- W3159995379 hasConcept C178790620 @default.
- W3159995379 hasConcept C185592680 @default.
- W3159995379 hasConcept C188027245 @default.
- W3159995379 hasConcept C192562407 @default.
- W3159995379 hasConcept C32909587 @default.
- W3159995379 hasConcept C42360764 @default.
- W3159995379 hasConcept C44228677 @default.
- W3159995379 hasConcept C521977710 @default.
- W3159995379 hasConcept C61048295 @default.
- W3159995379 hasConcept C93275456 @default.