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- W3160142130 abstract "Lithium iron phosphate is a cathode candidate material for Li-ion-batteries, which provides (i) stability during cycling and (ii) reduced risk of thermal runaway. However, disadvantages as (i) slow solid state diffusion and (ii) poor electrical conductivity reduce power capability. Improvement requires identification of the rate determining process. Electrochemical impedance spectroscopy (EIS) has proven to be a powerful tool for the exploration of electrochemical systems. The resolution of electrochemical processes can be enhanced in the frequency domain by applying the DRT-method (distribution of relaxation times). The DRT-method was developed and demonstrated for high-temperature fuel cells [1, 2]. For the first time, the benefits will be presented for the exploration of Li-ion-batteries. Measurements in a wide frequency range (10 mHz to 1 MHz) have been conducted on experimental LiFePO4cells with metallic lithium as anode (half cell). The study covers a variation of temperature (0 to 40 °C) and state of charge (10 to 90 %)." @default.
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- W3160142130 date "2010-01-01" @default.
- W3160142130 modified "2023-09-23" @default.
- W3160142130 title "Studies on LiFePO4 as Cathode Materials in Lithium-Ion-Batteries" @default.
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- W3160142130 doi "https://doi.org/10.1149/ma2010-01/3/144" @default.
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