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- W3160331617 abstract "Pd/ZnO catalysts show good activity and high selectivity to methanol during catalytic CO2 hydrogenation. The Pd-Zn alloy phase has usually been considered as the active phase, though mechanistic studies under operando conditions have not been conducted to verify this. Here, we report a mechanistic study under realistic conditions of methanol synthesis, using in situ and operando X-ray absorption spectroscopy, X-ray powder diffraction, and time-resolved isotope labeling experiments coupled with FTIR spectroscopy and mass spectrometry. Pd-Zn alloy-based catalysts, prepared through reduction of a heterobimetallic PdII ZnII acetate bridge complex, and which do not contain zinc oxide or any PdZn/ZnO interface, produce mostly CO. The Pd-Zn phase is associated with the formation of CO, and does not provide the active sites required to produce methanol from the direct hydrogenation of carbon dioxide. The presence of a ZnO phase, in contact with a Pd-Zn phase, is essential for efficient methanol production." @default.
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- W3160331617 date "2021-06-24" @default.
- W3160331617 modified "2023-10-02" @default.
- W3160331617 title "Mechanistic Study of Carbon Dioxide Hydrogenation over Pd/ZnO‐Based Catalysts: The Role of Palladium–Zinc Alloy in Selective Methanol Synthesis" @default.
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- W3160331617 doi "https://doi.org/10.1002/anie.202103087" @default.
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