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• W3160476504 endingPage "126184" @default.
• W3160476504 startingPage "126184" @default.
• W3160476504 abstract "Preparation of α-hemihydrate gypsum (α-HH) from phosphogypsum (PG) by atmospheric hydrothermal method has a good application prospect due to the mild reaction conditions, the solution medium and modifier are important factors to control the formation and growth of α-HH crystals. In this study, the mixed solutions of glycerol and Na2SO4 was proposed to transform PG into α-HH and the conversion mechanism was revealed, the morphology of α-HH was regulated by citric acid and its adsorption mechanism was clarified. The results show that the increase of glycerol and Na2SO4 concentrations could accelerate the conversion of PG to α-HH, but this caused a decrease in the particles size of α-HH. The conversion of PG to α-HH in the mixed solutions will successively pass through dissolution, dissolution-crystallization and equilibrium three stages. With the increase of citric acid concentration, the α-HH crystals are enlarged in width and decreased in aspect ratio, which is attributed to citric acid could overcome the electrostatic repulsion by the carboxyl group chelating with the calcium atoms to adsorb on the surface of α-HH." @default.
• W3160476504 created "2021-05-24" @default.
• W3160476504 creator A5038802926 @default.
• W3160476504 creator A5078808098 @default.
• W3160476504 date "2021-08-01" @default.
• W3160476504 modified "2023-10-01" @default.
• W3160476504 title "Preparation of α-hemihydrate gypsum from phosphogypsum in glycerol and Na2SO4 mixed solutions under atmospheric pressure" @default.
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• W3160476504 doi "https://doi.org/10.1016/j.jcrysgro.2021.126184" @default.
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