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- W3160743061 abstract "Gold(I)-catalyzed reactions of electron-poor alkynes are still a challenging process. A straightforward synthesis of phosphorus-based heterocycles, namely, 2-phenyl 1H-isophosphinoline 2-oxides 1, is reported. The reaction used PPh3AuCl precatalyst in combination with triflic acid under microwave activation and afforded isophosphinoline 2-oxides 1 in moderate to quantitative yields through a fully regioselective 6-endo-dig hydroarylation cyclization, paving the way toward an effective synthesis of phosphorus heterocycles." @default.
- W3160743061 created "2021-05-24" @default.
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- W3160743061 date "2021-05-19" @default.
- W3160743061 modified "2023-10-18" @default.
- W3160743061 title "Gold-Catalyzed Access to Isophosphinoline 2-Oxides" @default.
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- W3160743061 doi "https://doi.org/10.1021/acs.joc.1c00648" @default.
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