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- W3161184001 abstract "We successfully achieved the synthesis of C60-xanthlium, X60_NTf2, where fullerene is an electron donor and xanthlium is an electron acceptor. When the precursor compound X60-OH was excited at 550 nm, the C60 emission was observed at 715 nm. On the other hand, the fluorescence of X60_NTf2 was completely quenched under the same conditions, suggesting that photo-induced intramolecular electron transfer (ET) occurred from the singlet excited state of C60. The electrochemical measurement proved that the X60_NTf2 is exothermically possible of ET reaction from 1C60* to xanthylium to form C60.+. Density functional theory (DFT) calculations support the acceptor ability of the xanthylium by showing that the coefficients of the lowest unoccupied molecular orbital (LUMO) were on xanthene moiety. This is a well-arranged model compound to investigate the properties of transiently generated fullerene radical cations." @default.
- W3161184001 created "2021-05-24" @default.
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- W3161184001 date "2021-05-22" @default.
- W3161184001 modified "2023-09-25" @default.
- W3161184001 title "Buckyball as an Electron Donor in a Dyad of C <sub>60</sub> and Xanthene Dye" @default.
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- W3161184001 doi "https://doi.org/10.1002/ejoc.202100276" @default.
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