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• W3161916976 abstract "Aminofutalosine synthase (MqnE) is a radical SAM enzyme that catalyzes the conversion of 3-((1-carboxyvinyl)oxy)benzoic acid to aminofutalosine during the futalosine-dependent menaquinone biosynthesis. In this Communication, we report the trapping of a radical intermediate in the MqnE-catalyzed reaction using sodium dithionite, molecular oxygen, or 5,5-dimethyl-1-pyrroline-N-oxide. These radical trapping strategies are potentially of general utility in the study of other radical SAM enzymes." @default.
• W3161916976 created "2021-05-24" @default.
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• W3161916976 date "2021-05-17" @default.
• W3161916976 modified "2023-10-06" @default.
• W3161916976 title "Menaquinone Biosynthesis: New Strategies to Trap Radical Intermediates in the MqnE-Catalyzed Reaction" @default.
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• W3161916976 doi "https://doi.org/10.1021/acs.biochem.1c00181" @default.
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