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- W3162032333 abstract "The bilayer structure of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) coating on silver nanowires (AgNWs) film is a promising structure for replacing indium tin oxide (ITO) as a flexible transparent conductive electrode. Pristine PEDOT:PSS film due to its hydrophilicity and high permeability cannot fully protect AgNWs from mechanical stress and oxidation. Here, we present a composite approach that improves mechanical properties and lifespan of the AgNWs/PEDOT:PSS electrode by adding polyvinyl alcohol (PVA) as a polymer-surfactant. It is shown that addition of PVA improves the conductivity as well as the stability of hybrid electrode under demanding mechanical stress conditions. The drop in conductivity of the hybrid electrode is only 17% after 2000 repeated bending cycles whereas the reference electrode has shown a dramatic drop of 180% in the conductivity. We speculate that generation of hydrogen bonds between PEDOT:PSS and PVA increases adhesivity and cohesivity of the conductive polymer film to the sublayer. So PEDOT:PSS-PVA film not only fixes the arrangement of AgNWs but also improves the welding on cross junction points. By addition of PVA, optoelectronic performance (Figure-of-merit (Φ TC )) of the electrode is improved from Φ TC = 2.646 × 10 -3 Ω -1 for AgNWs/PEDOT:PSS to Φ TC = 3.819 × 10 -3 Ω -1 for AgNWs/PEDOT:PSS-PVA electrode and power conversion efficiency (PCE) of the polymer solar cell (PSC) is increased by over 17%. • The optoelectronic, mechanical properties and electrode longevity were improved by innovative addition of polymer surfactant. • The behavior of the PEDOT:PSS film was changed from brittle to ductile and tested in harsh mechanical stresses. • The permeability of the PEDOT:PSS film was reduced by increasing the packing of the polymer chains. • By enhancing the adhesivity of the PEDOT:PSS film, the welding of AgNWs in cross junction points was improved. • By strengthening the adhesion force of the PEDOT:PSS film, AgNWs arrangement was also fixed under mechanical stresses." @default.
- W3162032333 created "2021-05-24" @default.
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- W3162032333 date "2021-08-01" @default.
- W3162032333 modified "2023-10-16" @default.
- W3162032333 title "Mechanically stable solution-processed transparent conductive electrodes for optoelectronic applications" @default.
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- W3162032333 doi "https://doi.org/10.1016/j.synthmet.2021.116805" @default.
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