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- W3162092571 abstract "Asymmetric reduction of aromatic keto acid was achieved with sodium borohydride (NaBH4) in the presence of newly prepared 6-deoxy-phenylethylamino-β-cyclodextrin (PEACD) gave a high optical yields of around 40% enantiomeric excess (40% e.e.). Based upon the dependence of asymmetric selectivity of PEACD with benzoyl formic acid (BFA), p-hydroxyphenylpyruvic acid (pHPPA) and indole-3-pyruvic acid (IPA) controlled asymmetric reaction which indicates the balance between the electrostatic interaction, hydrogen bonding and steric hindrance enhanced the host-guest complexes. Furthermore, the orientation of various guest molecules in host CD cavity were governed by the molecular shape of the guest or by interaction between the guest α-keto acid and the cavity shape of host CD. This provides multiple interaction, and the induced mechanism of asymmetric selective differentiating reduction which was suggested with the host-guest inclusion complexes on molecule recognition." @default.
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- W3162092571 date "2010-01-01" @default.
- W3162092571 modified "2023-09-28" @default.
- W3162092571 title "Controlled Asymmetric Reduction of Various α-Keto Acids using NaBH4 with 6-Deoxy-phenylethylamino-β-cyclodextrin in Aqueous Solution" @default.
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