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- W3162473416 abstract "It is still a challenge to design and synthesize novel switchable optical materials with ultrafast nonlinear optical (NLO) response in a broad spectral range. These materials have exhibited great application potential in many high-technology fields such as biological imaging, chemical sensors, optical data storage, laser protection, and controllable intelligent and optoelectronic devices. By using porphyrins with highly delocalized 18 π-electron conjugated system as functional building blocks, the first ether-linked porphyrin covalent organic framework materials (COF-Pors) with highly ordered lattice structure have been successfully synthesized. In contrast to the starting porphyrins that only exhibit reverse saturable absorption (RSA) response at 532 nm, the as-prepared COF-Pors shows large NLO effect in a broad range from visible to near infrared. Upon laser illumination, COF-Pors exhibits typical saturable absorption (SA) effect at lower incident laser energy, and RSA response at higher pulse energy." @default.
- W3162473416 created "2021-05-24" @default.
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- W3162473416 date "2021-06-01" @default.
- W3162473416 modified "2023-10-15" @default.
- W3162473416 title "Ether-linked porphyrin covalent organic framework with broadband optical switch" @default.
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- W3162473416 doi "https://doi.org/10.1016/j.isci.2021.102526" @default.
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