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• W3162910922 endingPage "120459" @default.
• W3162910922 startingPage "120459" @default.
• W3162910922 abstract "The reaction of metal precursors of the type [( p -cymene)RuCl 2 ] 2 and [Cp*MCl 2 ] 2 (M = Rh/Ir) with coumarin- N -acylhydrazone ligands ( L1 , L2 and L3 ) yielded neutral bidentate (N∩O) complexes ( 1 – 9 ). These complexes were characterized by various spectroscopic techniques and also studied for biological activities. • Coumarin- N -acylhydrazones with metal dimers resulted neutral mononuclear complexes. • Complexes 3, 4, 5, 6 and ligand L3 showed highest antibacterial activity. • Complexes 1, 3 and 6 showed highest antioxidant activity. • Complex 6 shows a significant binding tendency towards DNA. A series of half-sandwich platinum group metal complexes containing coumarin- N -acylhydrazone ligands have been prepared. The metal precursors of the type [( p -cymene)RuCl 2 ] 2 and [Cp*MCl 2 ] 2 (M = Rh/Ir) and coumarin- N -acylhydrazone ligands ( L1 , L2 and L3 ) were reacted in the ratio of 1:2 (M:L), forming neutral bidentate (N ∩ O) complexes ( 1 – 9 ). The complexes are of the general formula [(arene)M{κ 2 (N∩O) L}Cl]. All these complexes have been characterized by analytical, spectroscopic and single-crystal X-ray diffraction studies. The complexes and ligands were then carried out for antibacterial, antioxidant and DNA binding studies. The results show that both ligands and complexes possess potent antibacterial and antioxidant properties. ___________________________________________________________________________" @default.
• W3162910922 created "2021-05-24" @default.
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• W3162910922 date "2021-09-01" @default.
• W3162910922 modified "2023-10-01" @default.
• W3162910922 title "Half-sandwich platinum group metal complexes containing coumarin-N-acylhydrazone hybrid ligands: Synthesis and biological evaluation studies" @default.
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• W3162910922 doi "https://doi.org/10.1016/j.ica.2021.120459" @default.
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