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- W316297032 abstract "The title compounds, trans-dichlorobis[(1R,2R,3R,5S)-(-)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-amine]palladium(II), [PdCl2(C10H19N)2], and trans-dichlorobis[(1S,2S,3S,5R)-(+)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-amine]palladium(II) hemihydrate, [PdCl2(C10H19N)2].0.5H2O, present different arrangements of the amine ligands coordinated to PdII, viz. antiperiplanar in the former case and (-)anticlinal in the latter. The hemihydrate is an inclusion compound, with a Pd coordination complex and disordered water molecules residing on crystallographic twofold axes. The crystal structure for the hemihydrate includes a short Pd...Pd separation of 3.4133 (13) A." @default.
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- W316297032 date "2005-08-20" @default.
- W316297032 modified "2023-09-27" @default.
- W316297032 title "Conformational change induced by hydration:<i>trans</i>-dichlorobis[(1<i>R</i>,2<i>R</i>,3<i>R</i>,5<i>S</i>)-(–)-isopinocampheylamine]palladium(II) and<i>trans</i>-dichlorobis[(1<i>S</i>,2<i>S</i>,3<i>S</i>,5<i>R</i>)-(+)-isopinocampheylamine]palladium(II) hemihydrate" @default.
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- W316297032 doi "https://doi.org/10.1107/s0108270105024315" @default.
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